The crystal field splitting energy of
complex is '
times that of the
complex. Here ' n ' is
. (Assume
)
Text Solution
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The Crystal Field Stabilization Energy (CFSE) is calculated based on the electronic configuration of the central metal ion in the octahedral field.
For
:
Cobalt is in +3 oxidation state.
has a
configuration.
Given
, it is a low spin complex. The electrons fill the
level first.
Configuration:
.
CFSE for
.
For
:
Chromium is in +3 oxidation state.
has a
configuration.
Configuration:
.
CFSE for
.
Comparing the magnitudes of the stabilization energies:
Magnitude of CFSE for
.
Magnitude of CFSE for
.
The ratio
.
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